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Chemical compound
Phenylacetylene is an alkyne hydrocarbon containing a phenyl group. It exists as a colorless, viscous liquid. In research, it is sometimes used as an
Phenylacetylene
Hydrocarbon compound containing one or more C≡C bonds
which are first halogenated and then dehydrohalogenated. For example, phenylacetylene can be generated from styrene by bromination followed by treatment
Alkyne
Chemical reaction used to synthesize aryl halides from aryl diazonium salts
Swiss chemist Traugott Sandmeyer, when he attempted to synthesize phenylacetylene from benzenediazonium chloride and copper(I) acetylide. Instead, the
Sandmeyer_reaction
Chemical compound
trimethylsilyl group can then be cleaved off with TBAF or DBU to form phenylacetylene derivatives. Trimethylsilylacetylene is also used to synthesize diphenylacetylene
Trimethylsilylacetylene
Chemical reaction between molecular hydrogen and another compound or element
alkenes. The Lindlar catalyst has been applied to the conversion of phenylacetylene to styrene. Illustrative hydrogenations Selective hydrogenation of
Hydrogenation
Hydrocarbon compound (C6H6)
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Benzene
Chemical compound
benzaldehyde, or may also be viewed as a formylated derivative of phenylacetylene. 4-Ethynylbenzaldehyde may be prepared by the Sonogashira coupling
4-Ethynylbenzaldehyde
Chemical compound
the diyne chemical class and can be made via the Glaser coupling of phenylacetylene However, a variety of other synthesis methods have been developed.
Diphenylbutadiyne
Cross-coupling reaction used in organic synthesis
reaction. Acetylene is activated in the second, PdII mediated cycle. Phenylacetylene was proven to form Pd monoacetylide complex D as well as Pd bisacetylide
Sonogashira_coupling
Chemical compound
salt of phenylacetylene in the Castro-Stephens coupling. The related Sonogashira coupling involves the coupling of iodobenzene and phenylacetylene. Diphenylacetylene
Diphenylacetylene
Catalyst enabling the hydrogenation of alkynes to alkenes
only the triple bond is reduced. An example being the reduction of phenylacetylene to styrene. Alkyne hydrogenation is stereospecific, occurring via syn
Lindlar_catalyst
Rule for predicting outcomes of some addition reactions
alkenes. Anti-Markovnikov behaviour is observed in the hydration of phenylacetylene by auric catalysis, which gives acetophenone; although with a special
Markovnikov's_rule
Organic compound consisting entirely of hydrogen and carbon
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Hydrocarbon
Chemical compound
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Styrene
Chemical compound
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Naphthalene
Chemical compound
Tricarbonyl(mesitylene)molybdenum can act as a catalyst for the polymerisation of phenylacetylene. The Molybdenum complex is activated with an oxidant such as chloranil
(Mesitylene)molybdenum tricarbonyl
(Mesitylene)molybdenum_tricarbonyl
Index of chemical compounds with the same molecular formula
exact mass: 102.0470 u) may refer to: Benzocyclobutadiene Pentalene Phenylacetylene Calicene, or triapentafulvalene Cubene This set index page lists chemical
C8H6
Compound containing rings with delocalized pi electrons
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Aromatic_compound
Chemical reaction in organic chemistry
cyclooctadecanonaene. Another example is the synthesis of diphenylbutadiyne from phenylacetylene. The Hay coupling is variant of the Glaser coupling. It relies on the
Glaser_coupling
Chemical compound
which melt at 136–137 °C. When heated with water to 120 °C, it yields phenylacetylene (C6H5CCH). Chromic acid oxidizes it to benzoic acid; zinc and acetic
Phenylpropiolic_acid
Organic compounds with the formula (CH3)2C6H4
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Xylene
Chemical compound
dibromoalkane to give a carbon–carbon triple bond, as in a preparation of phenylacetylene. Usually two equivalents of sodium amide yields the desired alkyne
Sodium_amide
Materials that have a negative Poisson's ratio
Kenneth E. (2017). "On the Structural and Mechanical Properties of Poly(Phenylacetylene) Truss-Like Hexagonal Hierarchical Nanonetworks". Physica Status Solidi
Auxetics
Saturated alicyclic hydrocarbon
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Cycloalkane
Hydrocarbon compound made of a 5-carbon chain with two single and two double bonds
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Pentadiene
Chemical reaction
(1905). "Action of potassium hydroxide on mixtures of ketones and phenylacetylene". Zhurnal Russkago Fiziko-Khimicheskago Obshchestva. 37: 643–645.,
Favorskii_reaction
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Diisobutene
Unsaturated hydrocarbon compound (H2C=C(CH3)2)
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Isobutylene
Aromatic hydrocarbon
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Toluene
Chemical compound
substituents. In a classic example of click chemistry, phenyl azide and phenylacetylene react to give diphenyl triazole. Phenyl azide reacts with triphenylphosphine
Phenyl_azide
Chemical compound
using metal-alkyne complexes. Example, the reaction of mesitylene with phenylacetylene: Gold(III) chloride can be used for the direct oxidation of primary
Gold(III)_chloride
Chemical compound
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Cyclohexyne
Organometallic compound containing carbon–silicon bonds
"Effect of the synthetic method of Pt/MgO in the hydrosilylation of phenylacetylene" (PDF). Arkivoc. 126: 136. Linderman, Russell J.; Stiasni, Nikola;
Organosilicon_chemistry
Type of saturated hydrocarbon compound
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Alkane
Hydrocarbon compound containing one or more C=C bonds
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Alkene
Petrochemical process to break down saturated hydrocarbons in smaller molecules
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Steam_cracking
Chemical compound
Perkin Transactions 1 (4): 459–461. doi:10.1039/b110983a. Reagents: phenylacetylene, Schwartz's reagent, tetraphenylpalladium and the iodane
Schwartz's_reagent
Chemical compound
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Cyclopropyne
Covalent compound that contains two double bonds
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Diene
Chemical compound
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
2,2,4-Trimethylpentane
Chemical compound
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Methylcyclopropane
Chemical compound
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Spiropentadiene
Chemical compound
10-methylphenothiazine cation radical perchlorate in solutions of phenylacetylene and p-tolylacetylene in acetonitrile". The Journal of Organic Chemistry
1,2-Dioxin
Chemical compounds
"Effect of the synthetic method of Pt/MgO in the hydrosilylation of phenylacetylene". Arkivoc: 126–136. ISSN 1424-6376 – via ResearchGate. Chatgilialoglu
Hydrosilanes
Organic compounds with the empirical formula CH3C6H4CH2CH3
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Ethyltoluene
Chemical compound
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Butadiene
Nanoclusters
Songhai; Tsukuda, Tatsuya (2011). "Organogold Clusters Protected by Phenylacetylene". Journal of the American Chemical Society. 133 (50): 20123–20125.
Monolayer-protected cluster molecules
Monolayer-protected_cluster_molecules
Chemical compound
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Anthracene
American chemist (born 1962)
to discover new polymers. Some of Moore's early work utilized the phenylacetylene moiety in the construction of nanoscale structures such as macrocycles
Jeffrey_S._Moore
Chemical reaction
Farid, Samir (1980). "Photosensitized electron-transfer reactions of phenylacetylene". Journal of the Chemical Society, Chemical Communications (3): 126
Ritter_reaction
Copper iron mixed oxide mineral
published in a research towards the A3 coupling of aldehydes, amine with phenylacetylene to give the corresponding propargylamines. The catalyst can be reused
Cuprospinel
Polycyclic aromatic hydrocarbon composed of three fused benzene rings
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Phenanthrene
Chemical compound
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Methylcyclobutane
Hydrocarbon compound (C22H14) made of 5 fused benzene rings
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Pentacene
Organic compound
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Cumene
Organic ion with a negatively charged carbon atom
Fluoroform CHF3 30.5 Xanthene C13H10O 30.0 Ethanol (O–H) C2H5OH 29.8 Phenylacetylene C8H6 28.8 Thioxanthene C13H10S 28.6 Acetone C3H6O 26.5 Chloroform CHCl3
Carbanion
Chemical compound
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
4-Vinyltoluene
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Pentadienyl
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Cymene
Hydrocarbon compound; precursor to styrene and polystyrene
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Ethylbenzene
Chemical compound
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Azulene
Chemical compound
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
P-Xylene
American chemist (1893–1978)
properties of hydrocarbons as very weak acids, including acetophenone, phenylacetylene, fluorene and diphenylmethane. Conant can be considered alongside Brønsted
James_B._Conant
Study of compounds containing gold–carbon bonds
-vinyls are not susceptible to β hydride elimination. The hydration of phenylacetylene to acetophenone using tetrachloroauric acid in a 37% yield was reported
Organogold_chemistry
Class of chemical compounds
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Acene
Chemical compound
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Cyclobutyne
Chemical compound
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
1,2,4-Trimethylbenzene
Chemical compound
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
4-Ethyltoluene
Chemical compound
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
P-Cymene
Group of isomeric chemical compounds
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Trimethylbenzene
Chemical compound
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Methylcyclopentane
Chemical compound
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Mesitylene
Chemical reaction
PK reaction has poor regioselectivity with monosubstituted alkenes. Phenylacetylene and 1-octene produce at least 4 isomeric products. ("tol" = toluene)
Pauson–Khand_reaction
Chemical compound
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Pyrene
Chemical compound
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
O-Xylene
Chemical compound
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Isobutylbenzene
Chemical compound
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Prismane
Family of organic compounds
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Alkylbenzene
Chemical reaction of three alkynes to form a benzene ring
of unsymmetrical alkynes gives two isomeric benzenes. For example, phenylacetylene affords both 1,3,5- and 1,2,4-C6R3H3. The substitution pattern about
Alkyne_trimerisation
Organic compound, C6H4(CH=CH2)2
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Divinylbenzene
Hydrocarbon composed of multiple aromatic rings
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Polycyclic aromatic hydrocarbon
Polycyclic_aromatic_hydrocarbon
Organic compound
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Prehnitene
Index of chemical compounds with the same name
xylenes") Styrene Phenylacetylene 1,2-Dimethylbenzene 1,3-Dimethylbenzene 1,4-Dimethylbenzene Ethylbenzene Styrene Phenylacetylene This set index article
C2-Benzenes
Chemical compound
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Trans-Propenylbenzene
Chemical compound
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
1,5-Hexadiene
Hydrocarbon ring molecule containing a C≡C bond
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Cycloalkyne
Chemical compound
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Spiropentane
Group of chemical compounds
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Tetramethylbenzene
Chemical compound
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
N-Propylbenzene
Chemical compound
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Tetracene
cubene radical 77478-10-5 C8H6 cyclooctatrienyne radical 4514-69-6 C8H6 phenylacetylene 536-74-3 C8H6Cl2O3 dicamba 1918-00-9 C8H6Cl3NO3 triclopyr methyl ester
List of compounds with carbon number 8
List_of_compounds_with_carbon_number_8
Chemistry of compounds with W-C bonds
Sundararajan, Govindarajan (1997-10-01). "Metathesis Polymerization of Phenylacetylene by Arene Metal Tricarbonyl Complexes Promoted by Chloranil Acceptor"
Organotungsten_chemistry
Hydrocarbon compound containing a non-aromatic ring with a C=C bond
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Cycloalkene
Chemical compound
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Nonacene
Hydrocarbon compound with 3 or more consecutive double bonds
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Cumulene
Addition reaction
Nef in 1899 while experimenting with reactions of elemental sodium, phenylacetylene, and acetophenone. For this reason, the reaction is sometimes referred
Alkynylation
Chemical compound
formed analogously. The [2+2]cycloaddition of diphenyl ketene with phenylacetylene leads first to a cyclobutenone which thermally aromatizes to a phenyl
Diphenylketene
Organic compound
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Sec-Butylbenzene
Chemical compound
Styrene Divinylbenzene 4-Vinyltoluene Other Benzene Cyclopropenylidene Phenylacetylene trans-Propenylbenzene Other Annulenes Annulynes Alicyclic compounds
Hexamethylbenzene
Chemical compound
cyclotrimerization of a disilyne (Si-Si triple bonded species) and phenylacetylene. Some theoretical studies suggest that the symmetric 1,3,5-trisilabenzene
Silabenzene
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