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Type of compound
Phosphinidenes (IUPAC: phosphanylidenes, formerly phosphinediyls) are low-valent phosphorus compounds analogous to carbenes and nitrenes, having the general
Phosphinidene
4-coordinate silicon, which can also be viewed as silylene-stabilized phosphinidene, can be synthesized based on the reactivities of stable silyene complexes
Phosphasilene
Chemical compound
Wolczanski, Peter T.; Lobkovsky, Emil B. (1994-11-01). "Arsinidene, Phosphinidene, and Imide Formation via 1,2-H2-Elimination from (silox)3HTaEHPh (E
Tris(silox)tantalum
Chemical compound
phosphanido, or dihydridophosphato(1−). A related substance has PH2−. Phosphinidene (PH) has phosphorus in a −1 oxidation state. As a ligand PH2 can either
Phosphanide
reacting with main-group starting materials such as ylides, silylene, and phosphinidene to synthesize and isolate for further steps. As CO becomes a more common
Ketenyl_anion
recent synthesis reported in 2019 proceeds through the transfer of a phosphinidene species from dibenzo-7-(R)-7-phospha-norbornadiene (RPA) onto styrene
Phosphiranes
Molecular entity formed as an elementary step in a multi-step chemical reaction
Carbenoid Ion-neutral complex Keto anions Nitrenes Oxocarbenium ions Phosphinidenes Phosphoryl nitride Tetrahedral intermediates in carbonyl addition reactions
Reaction_intermediate
Chemical compound
monomeric intermediate fragment. The V-NP fragment undergoes singlet phosphinidene reactivity ([2+1] additions) with alkene and alkyne trapping agents
Phosphorus_mononitride
Type of chemical reaction
readily in cycloaddition reactions. Cycloaddition reactions of Ruthenium phosphinidenes with alkenes and alkynes is an active area research and has promise
Metal-centered cycloaddition reactions
Metal-centered_cycloaddition_reactions
Chemist
Massachusetts Institute of Technology Harvard University Thomas J. Watson Research Center Thesis Studies of terminal phosphinidene complexes of zirconium (1996)
Tricia_Carmichael
American chemist
chemistry; especially their use in stabilizing carbenes, nitrenes, phosphinidenes, radicals and biradicals, 1,3-dipoles, anti-aromatic heterocycles, and
Guy_Bertrand_(chemist)
American chemist
University of Chicago Thesis The chemistry of three-coordinate nickel phosphinidene, imido, and carbene complexes (2004) Doctoral advisor Gregory L. Hillhouse
Rory_Waterman_(chemist)
Power, Philip P. (October 1986). "Synthesis and characterization of the phosphinidene borate complexes [Li(Et2O)2PRB(Mes)2] and [Li(12-crown-4)2][RPB(Mes)2]
Group_13/15_multiple_bonds
Bertrand (born 1952) French chemist working on carbenes, nitrenes, phosphinidenes, radicals and biradicals Jöns Jakob Berzelius (1779–1848), Swedish chemist
List_of_chemists
Study of magnesium compounds in chemistry
give dibenzo-7λ3-phosphanorbornadiene (RPC14H10), which can be used as phosphinidene transfer reagent. The first characterized N-heterocyclic carbene (NHC)
Organomagnesium_chemistry
Chemical compound
to give complexes and clusters. It is the precursor to the bridging phosphinidene ligand in certain clusters. 2 (C6H5)2MCl + C6H5PH2 + 3 (C2H5)3N → ((C6H5)2M)2PC6H5
Phenylphosphine
British chemistry professor (born 1974)
"Triamidoamine-Uranium(IV)-Stabilized Terminal Parent Phosphide and Phosphinidene Complexes". Angewandte Chemie. 53: 4484-4488. doi:10.1002/anie.201400798
Stephen_Liddle
proceed via metal phosphido intermediates. Some however proceed by metal-phosphinidene intermediates, i.e. species with M=PR double bonds. One such example
Hydrophosphination
Class of positively-charged molecules
R2N+ (protonated nitrenes) phosphinidenium cations, R2P+ (protonated phosphinidene) mercurinium cations, R3Hg+ (protonated organomercury compounds; formed
Onium_ion
Chemical compound
Fischer; Andre Mitschler (1982). "Generation and Trapping of Terminal Phosphinidene Complexes. Synthesis and X-ray Crystal Structure of Stable Phosphirene
Phosphirene
Chemical compound
Complexes and Electron-Donating Properties of N-Heterocyclic-Carbene–Phosphinidene Adducts". European Journal of Inorganic Chemistry. 2016 (23): 3704–3713
Pentacarbonyl(tetrahydrofuran)tungsten
Pentacarbonyl(tetrahydrofuran)tungsten
American inorganic chemist
Daniel J.; Hillhouse, Gregory L. (2002). "Monomeric Phosphido and Phosphinidene Complexes of Nickel". Journal of the American Chemical Society. 124
Gregory_L._Hillhouse
Family of chemical compounds
higher C-P bond character, and therefore better π-backbonding from the phosphinidene to the CAAC ligands. By correlation to the TEPs for these complexes
Cyclic_alkyl_amino_carbenes
Organophosphorus compound with a phosphorus–phosphorus double bond
conjugation caused the compounds to exhibit reactivity closer to a phosphinidene. Cyclic voltammetry and UV/Vis spectra indicate that boryl-substituted
Diphosphenes
Divalent cations of phosphorus
electrophiles with [(η5-C5Me5)Fe(CO)2]−; spectroscopic evidence for a phosphinidene complex". Inorganic Chemistry. 23 (22): 3431–3433. doi:10.1021/ic00190a001
Phosphenium
Class of carbon compounds
(2013). "Chiral heterobimetallic complexes of carbodiphosphoranes and phosphinidene–carbene adducts". Chemical Communications. 49 (30): 3140–3142. doi:10
Carbodicarbenes
Group of carbenes
carbene analog (RN) is called a nitrene. The phosphorus analog is a phosphinidene. There are charged group 15 carbene analogs as well, most notably phosphenium
Carbene_analog
American chemist
carbene•cadmium, and carbene•lithium adducts. Reactions of carbenes with phosphinidenes were also reported from Arduengo's laboratory in addition to insertion
Anthony_J._Arduengo
Class of chemical compounds
Klaus; Meyer, H.-Jürgen (September 2011). "Phosphorus-Centered and Phosphinidene-Capped Tungsten Chloride Clusters". European Journal of Inorganic Chemistry
Phosphide_chloride
Chemical compound
synthesize free, uncomplexed phosphet-2-ones with high yield using a phosphinidene transfer agent derived from anthracene. The reactivity of the phosphet-2-ones
Phosphetene
Family of chemical compounds
Schneider, Sven (2019-03-06). "Interconversion of Phosphinyl Radical and Phosphinidene Complexes by Proton Coupled Electron Transfer". Angewandte Chemie. 131
Stable_phosphorus_radicals
"Reactions of Tri- tert -Butylphosphatetrahedrane as a Spring-Loaded Phosphinidene Synthon Featuring Nickel-Catalyzed Transfer to Unactivated Alkenes"
Pnictogen-substituted tetrahedranes
Pnictogen-substituted_tetrahedranes
Class of organobismuth compounds
formation of sp hybrid orbitals. In contrast, for the lighter congeners phosphinidenes, their smaller phosphorus 3s-3p energy gap favors a triplet ground state
Bismuthinidene
NZ–American physicist/chemist
Rhett C.; Protasiewicz, John D. (2001). "Three Different Fates for Phosphinidenes Generated by Photocleavage of Phospha-Wittig Reagents ArPPMe3". Journal
Cather_Simpson
PHOSPHINIDENE
PHOSPHINIDENE
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PHOSPHINIDENE
Girl/Female
Hindu, Indian, Tamil
Sky Spark
Boy/Male
Indian
One who seeks the right direction, Honoured, Admired
Boy/Male
Tamil
Vimalanathan | விமாலாநாதந
Lord Vishnu
Female
French
Feminine form of French Marin, MARINE means "of the sea."
Girl/Female
Muslim
Intimate friend, Companion
Boy/Male
Biblical
The wood of the man.
Girl/Female
British, English
Consecrated
Surname or Lastname
English
English : from a reduced pet form of the personal name Jacob.French : nickname for a good neighbor or amiable fellow worker, from Old French compain ‘companion’, ‘fellow’ (Late Latin companio ‘messmate’, genitive companionis, from con- ‘together’ + panis ‘bread’).Possibly also Irish or Scottish : reduced form of McCoppin.
Boy/Male
Hindu, Indian, Traditional
Indra's Banner
Boy/Male
Muslim
Harmony
PHOSPHINIDENE
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