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The Perkow reaction is an organic reaction in which a trialkyl phosphite ester reacts with a haloketone to form a dialkyl vinyl phosphate and an alkyl
Perkow_reaction
Chemical reaction
halide. The Perkow reaction is a competing reaction pathway for α-bromo- and α-chloroketones. Under the reaction conditions a mixture of the Perkow product
Michaelis–Arbuzov_reaction
synthesis Perkin reaction Perkin rearrangement Perkow reaction Petasis reaction Petasis reagent Peterson olefination Peterson reaction Petrenko-Kritschenko
List_of_organic_reactions
Chemical reaction in which a nucleophile is affixed to the substrate
ring-closing reaction of aminoalcohols. The Finkelstein reaction, a halide exchange reaction. Phosphorus nucleophiles appear in the Perkow reaction and the
Nucleophilic_substitution
Organic compound with the formula P(OR)3
phosphite esters are used in the Perkow reaction for the formation of vinyl phosphonates, and in the Michaelis–Arbuzov reaction to form phosphonates. Aryl phosphite
Phosphite_ester
Organic compound with at least one covalent carbon–phosphorus bond
reaction is general, thus a vast number of such species are known. Phosphites are employed in the Perkow reaction and the Michaelis–Arbuzov reaction.
Organophosphorus_chemistry
Formal ontology of chemical named reactions
RXNO:0000157 Nef reaction RXNO:0000183 Perkow reaction RXNO:0000193 Hiyama coupling RXNO:0000210 Fleming–Tamao oxidation RXNO:0000218 Cannizzaro reaction RXNO:0000288
RXNO_Ontology
Functional group in organic chemistry
enols with phosphites in the Perkow reaction. In crossed aldol reactions between halo ketones and aldehydes, the initial reaction product is a halohydrin which
Α-Halo_ketone
Chemical compound
hexachloroacetone in the preparation of a novel insect repellent (see Perkow reaction). The industrial route to hexafluoroacetone involves treatment of hexachloroacetone
Hexachloroacetone
Overview of and topical guide to organic chemistry
Mitsunobu reaction Perkow reaction Sandmeyer reaction Sharpless asymmetric dihydroxylation Sharpless oxyamination Solvolysis reaction Pinner reaction Swern
Outline_of_organic_chemistry
Chemical compound
1970. Wirksubstanzen der Pflanzenschutz und Schadlingsbekampfungsmittel, Perkow, W., Berlin, Verlag Paul Parey, 1971-1976Vol. -, Pg. -, 1971/1976. Bollettino
Α-Naphthylthiourea
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