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A germanide is any binary compound of germanium and a more electropositive element. The composition of most germanides is analogous to that of the corresponding
Germanide
Chemical compound
Cobalt germanide (CoGe) is an intermetallic compound, a germanide of cobalt. Cubic CoGe crystals (space group P213, cP8, a = 0.4631 nm) can be produced
Cobalt_germanide
Germanide halides are compound that include the germanide (Ge4−) anion and a halide such as chloride (Cl−), bromide (Br−) or iodide (I−). They include
Germanide_halide
Chemical compound
Manganese germanide (MnGe) is an intermetallic compound, a germanide of manganese. Its crystals have a cubic symmetry with no inversion center, they are
Manganese_germanide
Chemical compound
Iron germanide (FeGe) is an intermetallic compound, a germanide of iron. At ambient conditions it crystallizes in three polymorphs with monoclinic, hexagonal
Iron_germanide
Chemical compound
germyl or potassium trihydrogen germanide KGeH3) and rubidium compounds (rubidium germyl or rubidium trihydrogen germanide RbGeH3) have the sodium chloride
Germane
Crystallographic system where the unit cell is in the shape of a cube
the unit cell. Examples occur among the transition metal silicides and germanides, as well as a few other compounds such as gallium palladide. A Weaire–Phelan
Cubic_crystal_system
Chemical compound
SiGe (/ˈsɪɡiː/ or /ˈsaɪdʒiː/), or silicon–germanium, is an alloy with any molar ratio of silicon and germanium, i.e. with a molecular formula of the form
Silicon–germanium
Antimony germanides or antimonide germanides are compounds containing germanium and antimony along with one or more metals. Bonding is only partially
Antimony_germanides
Chemical element with atomic number 90 (Th)
arsenic, antimony, and bismuth) also form binary thorium compounds. Thorium germanides are also known. Thorium reacts with hydrogen to form the thorium hydrides
Thorium
Chemical element with atomic number 83 (Bi)
g. (Ca2+)22[Bi4]4−([Bi2]4−)4[Bi3−]8; see Ponou, Siméon (2006). "Germanides, Germanide-Tungstate Double Salts and Substitution Effects in Zintl Phases"
Bismuth
chloroform or benzene, but hydrolyses readily. Mixed anion compound germanide iodides are also known. Lide, D. R., ed. (2005). CRC Handbook of Chemistry
Germanium_iodides
Hypothetical charge of an atom if all its bonds to different atoms were fully ionic
g. (Ca2+)22[Bi4]4−([Bi2]4−)4[Bi3−]8; see Ponou, Siméon (2006). "Germanides, Germanide-Tungstate Double Salts and Substitution Effects in Zintl Phases"
Oxidation_state
Chemical element with atomic number 23 (V)
F.; Hulm, John K. (15 February 1953). "Superconducting Silicides and Germanides". Physical Review. 89 (4): 884. Bibcode:1953PhRv...89Q.884H. doi:10.1103/PhysRev
Vanadium
Chemical element with atomic number 32 (Ge)
+1 are found on the surface of oxides, or negative oxidation states in germanides, such as −4 in Mg 2Ge. Germanium cluster anions (Zintl ions) such as Ge2−4
Germanium
Class of chemical compounds
silicon could be considered as a semimetal. Related compounds include the germanide carbides, phosphide silicides, boride carbides and nitride carbides. Other
Silicide_carbide
Mathematical foam of equal-volume bubbles
trapped in the polyhedral cages. Some alkali metal hydrides silicides and germanides also form this structure, with silicon or germanium at nodes, and alkali
Weaire–Phelan_structure
mixed anion compounds. Related compounds include phosphide silicides, germanide phosphides, arsenide carbides, nitride carbides and silicide carbides
Phosphide_carbide
Chemical compound
Hazards Flash point Non-flammable Related compounds Other anions Cobalt germanide Other cations Iron silicide Manganese monosilicide Related compounds Cobalt
Cobalt_monosilicide
Group of highly reactive chemical elements
and tetrahedral Si4−4 ions. The chemistry of alkali metal germanides, involving the germanide ion Ge4− and other cluster (Zintl) ions such as Ge2−4, Ge4−9
Alkali_metal
Class of chemical compounds
pnictide compounds. Related compounds include the arsenide phosphides, germanide arsenides, arsenide carbides, and phosphide nitrides. Arsenide and nitride
Arsenide_nitride
Chemical element with atomic number 49 (In)
D. (1996). "Synthesis, Structure, and Bonding of Two Lanthanum Indium Germanides with Novel Structures and Properties". Inorganic Chemistry. 35 (9): 2616–22
Indium
Property of ions and molecules
Ethanethiolate 1495 Nitromethanide 1501 Arsinide 1502 Methanethiolate 1502 Germanide 1509 Trichloromethanide 1515 Formylmethanide 1533 Methylsulfonylmethanide
Proton_affinity
Magnetic materials with specific magnetic order
Lorentz TEM image of helical spin stripes in iron germanide (FeGe) at 90 K
Helimagnetism
Laboratory device for preparing gases
from decomposition of magnesium silicide) Germanes from germanides, e.g. magnesium germanide Stannanes from stannides, e.g. magnesium stannide Boranes
Kipp's_apparatus
Chemical compound
trihydrogermanide, trihydridogermyl or according to IUPAC Red Book: germanide is an anion containing germanium bounded with three hydrogens, with formula
Germyl
intermetallics' overall enthalpies of formation resemble silicides, not germanides or plumbides. YSn3 is an electrical superconductor below 7 K (−447.07 °F)
Yttrium_stannides
intermetallic carbides and borides. A few phases of ternary silicides, germanides, and phosphides are also known to exist. In going from the binary to ternary
Cr23C6_crystal_structure
Germanane has been produced in a two-step route starting with calcium germanide. From this material, the calcium is removed by de-intercalation with HCl
Germanane
Chemical compound with hydrogen and carbon group atoms
tetrahydride hydrogen silicide (silane) SiH4 germanium tetrahydride hydrogen germanide (germane) GeH4 tin tetrahydride hydrogen stannide (stannane) SnH4 lead
Group_14_hydride
Wire with a diameter in the nanometres
This such type of synthesis is widely used to synthesise metal silicide/germanide nanowires through VSS alloying between a copper substrate and a silicon/germanium
Nanowire
bonded to the silicon. Related compounds include the phosphide carbides, germanide phosphides, nitride silicides, and antimonide silicides. One preparation
Phosphide_silicide
2005 edition of the Nomenclature of Inorganic Chemistry
form of the element name has to be taken, e.g. germide for germanium as germanide refers to GeH− 3. Polyatomic cations of the same element are named as
IUPAC nomenclature of inorganic chemistry 2005
IUPAC_nomenclature_of_inorganic_chemistry_2005
Crystalline materials consisting of a single layer of atoms
structure. Germanane is produced in a two-step route starting with calcium germanide. From this material, the calcium (Ca) is removed by de-intercalation with
Single-layer_materials
(barringerite: IMA2016-086) 1.BB. [57] [no] [no] (IUPAC: dipalladium germanide) Palladosilicide (barringerite: IMA2014-080) 1.BB. [58] [no] [no] (IUPAC:
List of minerals recognized by the International Mineralogical Association (P–Q)
List_of_minerals_recognized_by_the_International_Mineralogical_Association_(P–Q)
Chemical compound
Hazards Flash point Non-flammable Related compounds Other anions Manganese germanide Other cations Iron silicide Cobalt silicide Related compounds Manganese
Manganese_monosilicide
360 b=4.3072 c=24.267 Z=4 1082.8 2.86 Ge5 rings black; actually is a germanide phosphide NaGe3P3 orthorhombic Pmc21 a=3.6276 b=8.407 c=10.332 Z=2 315
Phosphidogermanate
Any chemical compound having at least one germanium atom in its structure
+1 are found on the surface of oxides, or negative oxidation states in germanides, such as −4 in Mg 2Ge. Germanium cluster anions (Zintl ions) such as Ge42−
Germanium_compounds
2–10. Hardy, George; Hulm, John (1953). "Superconducting Silicides and Germanides". Physical Review. 89 (4): 884. Bibcode:1953PhRv...89Q.884H. doi:10.1103/PhysRev
A15_phases
Class of chemical compounds
"Diffusionless orthorhombic to hexagonal transitions in ternary silicides and germanides". Inorganic Chemistry. 14 (5): 1117–1120. doi:10.1021/ic50147a032. Bazela
Nickel_double_salts
Chemical compound
Hazards Flash point Non-flammable Related compounds Other anions Iron germanide Other cations Cobalt silicide Manganese silicide Except where otherwise
Iron_monosilicide
Chemical compound
produced by the reaction between hydrochloric acid and magnesium or calcium germanides-silicides, and by the reaction between hydrofluoric acid and a mixture
Silylgermane
Chemical compound
Corey, and Moore. Their method involves the hydrolysis of magnesium germanide using hydrochloric acid. Many of the properties of digermane and trigermane
Digermane
Chemical compound
and linear thermal expansitivities of platinum silicide and platinum germanide". Acta Crystallographica Section B: Structural Crystallography and Crystal
Platinum_silicide
IMA1996-050) 2.KA.10 [123] [124] [125] (IUPAC: dicopper (cadmium,iron) germanide tetrasulfide) Barrerite (zeolitic tectosilicate: IMA1974-017) 9.GE.15
List of minerals recognized by the International Mineralogical Association (B)
List_of_minerals_recognized_by_the_International_Mineralogical_Association_(B)
germanium in negative oxidation states −2 and −4 and so can be considered germanides as well. Reduced compounds may be produced by using a flux of molten sodium
Nitridogermanate
Chemical compound
ISBN 1-4398-5511-0. Rieger, W; Parthé, E (1967). "Alkaline earth silicides, germanides and stannides with CrB structure type". Acta Crystallographica. 22 (6):
Calcium_monosilicide
GERMANIDE
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