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Chemical compound
Disilane is a chemical compound with the chemical formula Si2H6 that was first identified in 1902 by Henri Moissan and Samuel Smiles (1877–1953). The term
Disilane
starting with silane, SiH4, the analogue of methane, continuing with disilane Si2H6, the analogue of ethane, etc. They are mainly of theoretical or academic
Binary silicon-hydrogen compounds
Binary_silicon-hydrogen_compounds
Chemical element with atomic number 46 (Pd)
Alvarez, S (2002). "Hexakis(silyl)palladium(VI) or palladium(II with eta2-disilane ligands?". Angewandte Chemie International Edition in English. 41 (11):
Palladium
Organic compound (H3C–CH3)
'tricarbane', and 'tetracarbane' as recommended for analogues of silane, 'disilane'; phosphane, 'triphosphane'; and sulfane, 'tetrasulfane'." "Ethane – Compound
Ethane
Flammable organic fuel (C4H10)
'tricarbane', and 'tetracarbane' as recommended for analogues of silane, 'disilane'; phosphane, 'triphosphane'; and sulfane, 'tetrasulfane'. W. B. Kay (1940)
Butane
Bonding of atoms of the same element into chains or rings
experimentally. Silicon can form sigma bonds to other silicon atoms (and disilane is the parent of this class of compounds). However, it is difficult to
Catenation
metals insert into the Si-Si bond of disilanes. The main limitation of this reaction is the paucity of disilanes as reagents. Bis(silyl)mercury reagents
Transition metal silyl complexes
Transition_metal_silyl_complexes
French chemist and pharmacist (1852–1907)
1907(1907-02-20) (aged 54) Paris, France Known for Isolation of fluorine Disilane Moissanite Strontium carbide Spouse Marie Léonie Lugan Moissan (m. 1882;
Henri_Moissan
Chemical compound
fluoride:[page needed] 6 NaH + 2 BF3 → B2H6 + 6 NaF Si–Si and S–S bonds in disilanes and disulfides are also reduced. A series of reduction reactions, including
Sodium_hydride
Hydrocarbon compound (C3H8)
'tricarbane', and 'tetracarbane' as recommended for analogues of silane, 'disilane'; phosphane, 'triphosphane'; and sulfane, 'tetrasulfane'. Lide, David R
Propane
Chemical compound
P403+P233, P405, P410+P403, P501 Related compounds Related compounds Ethane Disilane Dimethylsilane Trimethylsilane Tetramethylsilane Except where otherwise
Methylsilane
Chemical compound (SiH4)
Methane Germane Stannane Plumbane Related compounds Phenylsilane Vinylsilane Disilane Trisilane Except where otherwise noted, data are given for materials in
Silane
needed], the reaction has been demonstrated for the synthesis of certain disilanes as well as polysilanes. These reactions generally require catalysts. Titanocene
Dehydrogenative coupling of silanes
Dehydrogenative_coupling_of_silanes
Isoelectronic structure
that a B=B double bond is occurring. With specific reaction conditions, a disilane single or double bond can be achieved using the NHC boryl anion. To make
N-Heterocyclic carbene boryl anion
N-Heterocyclic_carbene_boryl_anion
NO2Cl −15 −145 81.5 13444-90-1 Chlorazide ClN3 −15 −100 77.47 13973-88-1 Disilane Si2H6 −14.8 −129.4 62 1590-87-0 Z-1,2,3,3,3-Pentafluoropropene CHF=CFCF3
List_of_gases
Chemical compound
+ 3LiAlH4 → Si6H12 + 3LiCl + 3AlCl3 Also, pyrolysis of monosilane and disilane by heating at low pressure followed by fractional distillation. Cyclohexasilane
Cyclohexasilane
Class of positively-charged molecules
silane) (should not be called siliconium) disilanium, Si2H+7 (protonated disilane) further silanium cations, Si nH+ 2n+3 (protonated silanes) germonium,
Onium_ion
Solid polymers of only silicon and hydrogen
monosilane (SiH4) and disilane (Si2H6). Polysilicon hydrides are intermediates in the high-temperature conversion of mono- and disilane to silicon and hydrogen
Polysilicon_hydride
Laboratory device for preparing gases
structure, sometimes more are produced from the same compound; e.g. silane, disilane and trisilane from decomposition of magnesium silicide) Germanes from germanides
Kipp's_apparatus
Chemical compound
(fire diamond) 2 4 1 Related compounds Related compounds Dimethyl ether Disilane Silane Silanol Trisilane Except where otherwise noted, data are given for
Disiloxane
Class of organosilicon compounds with the formula SiR4
also) includes silane itself but also compounds with Si-Si bonds including disilane and longer chains. Silanes with one, two, three, or four Si-H bonds are
Silanes
Chemical compound with hydrogen and carbon group atoms
which thermal stability decreasing as n increases (e.g. silane SiH4 and disilane Si2H6), as are cyclosilanes (e.g. cyclopentasilane Si5H10 and cyclohexasilane
Group_14_hydride
Chemical compound
polymerizes. As it is heated more silane is produced, and at 178°C it yields disilane. When heated to over 250°C it decomposes to a silicon hydrogen polymer
Cyclopentasilane
Silicon compounds with an Si=Si bond
5 to 10% shorter than the Si-Si single bond lengths of corresponding disilanes. A peculiarity of disilenes is the trans-bending of the substituents,
Silenes
Chemical reaction that converts an alkene to an alcohol
for terminal alkenes. Aside from boranes, the oxidation of silanes and disilanes can also yield hydroxy groups. A major difference is that while silyl
Hydroboration–oxidation reaction
Hydroboration–oxidation_reaction
tetrafluoride – SeF4 Selenium trioxide – SeO3 Selenoyl fluoride – SeO2F2 Disilane – Si2H6 Silane – SiH4 Silica gel – SiO2·nH2O Silicic acid – Si(OH)4 Silicochloroform
List_of_inorganic_compounds
Chemical compounds with at least one silicon atom
as SiH 4 and SiHCl 3 by Charles Friedel and Albert Ladenburg in 1867. Disilane (Si 2H 6) followed in 1902, when it was first made by Henri Moissan and
Silicon_compounds
Numbers, classes, and proper shipping names allocated to dangerous goods
batteries packed with equipment, with organic electrolyte UN 3553 2.1 Disilane UN 3554 8 Gallium contained in manufactured articles UN 3555 3
List of UN numbers 3501 to 3600
List_of_UN_numbers_3501_to_3600
Chemical compound
110 °C in xylene thereby releasing its strain energy[clarification needed]. Disilane Disilyne McCarthy, M. C.; Yu, Z.; Sari, L.; Schaefer, H. F.; Thaddeus,
Disilene
Chemical compound
magnesium silicide with 25% hydrochloric acid produces 40% monosilane, 30% disilane, 15% trisilane, 10% tetrasilane and 5% higher silanes. The mixture can
Tetrasilane
Allotrope of silicon
that link the silicene hexagons use disilyne bonding alternating with disilane bonding, analogous to polyyne. Phillip F. Schewe & Ben Stein (3 September
Silicyne
Chemical compound
3-bis(2,6-diisopropylphenyl)imidazolium fluoride. In combination with disilane, germanium tetrafluoride is used for in the synthesis of SiGe. Germanium(IV)
Germanium_tetrafluoride
Chemical compounds containing only hydrogen and one other chemical element
(silanes) is small (straight or branched but rarely cyclic) for example disilane and trisilane. For germanium only 5 linear chain binary compounds are known
Binary_compounds_of_hydrogen
Chemical reaction
Mori, I.; Nozaki, H. (1983), "Generation of metal-free silyl anions from disilanes and fluoride catalyst. Synthetic reactions with aldehydes and 1,3-dienes"
Hiyama_coupling
Chemical compound
NHSis insert into σ bonds to form terminal silane-like products, NHSi-NHSi disilane bridges, or oxo-bridged NHSi siloxanes. Alcohols react with Si(II) to form
N-heterocyclic_silylene
Chemical compound
pyrolysis has been found to be more endothermic than the pyrolysis of disilane. This difference is attributed to the greater strength of the Ge-H bond
Digermane
Any binary chemical compound containing just silicon and another chemical element
bonds are covalent. The parent, silane, is SiH4; higher homologues are disilane (Si2H6) and trisilane (Si3H8). Polysilicon hydride is a two-dimensional
Binary_compounds_of_silicon
Chemical compound
Fürstner, Alois; Weidmann, Hans (1988). "Efficient formation and cleavage of disilanes by potassium-graphite. Silylation with silyl metal reagents". Journal
Hexamethyldisilane
Chemical compound
are generally consistent with the absence of conventional triple bonds. Disilane Disilene Organosilicon compounds Egon Wiberg, Arnold Frederick Holleman
Disilyne
Chemical compound
mechanism, this decomposition proceeds by a 1,2 hydrogen shift that produces disilanes, normal and isotetrasilanes, and normal and isopentasilanes. Because it
Trisilane
controlled by annealing in the presence of an external silicon flux. By using disilane gas, the silicon vapor pressure can be controlled. SiC is bipolar and therefore
Epitaxial graphene growth on silicon carbide
Epitaxial_graphene_growth_on_silicon_carbide
Chemical compound
P403+P233, P405, P410+P403, P501 Related compounds Related compounds Ethane Disilane Digermane Methylsilane Methylgermane Except where otherwise noted, data
Silylgermane
They motivated this goals from recent reactivity study of silylene and disilane activating CO and isolating intermediate, hypothesizing that silica-ketenyl
Ketenyl_anion
K. Weichert (2007). "Synthesis and structure of titanium and zirconium disilane-1,2-diolates". Polyhedron. 31 (14): 3633-3637. doi:10.1016/j.poly.2007
Transition metal ether complex
Transition_metal_ether_complex
extended compared to the gas phase Si-Si bond length of 2.331Å in the parent disilane H3SiSiH3. Despite the long bond length, superdisilane exhibits thermal
Dispersion stabilized molecules
Dispersion_stabilized_molecules
DISILANE
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English : patronymic from Lawrence.Americanized form of any of various like-sounding Jewish surnames, as for example Levenson.
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