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CYCLOPROPANONE

Cyclopropanone

Chemical compound

Cyclopropanone is an organic compound with molecular formula (CH2)2CO consisting of a cyclopropane carbon framework with a ketone functional group. The

Cyclopropanone

Cyclobutanone

Chemical compound

(cycloalkanone). It is a colorless volatile liquid at room temperature. Since cyclopropanone is highly sensitive, cyclobutanone is the smallest easily handled cyclic

Cyclobutanone

Favorskii rearrangement

Chemical reaction

2-electron electrocyclization to the cyclopropanone. In either case, the base then attacks the cyclopropanone. Finally, the ring opens to yield the more

Favorskii rearrangement

Favorskii_rearrangement

Coprine

Chemical compound

1-aminocyclopropanol quickly converts to a reactive diol known as cyclopropanone hydrate, which binds covalently to the thiol present in the active site

Coprine

Hemiacetal

Organic compound of the form >C(OH)O–

Wiley & Sons, Inc. ISBN 978-1-119-24897-2. Salaun, Jacques (1983). "Cyclopropanone Hemiacetals". Chemical Reviews. 83 (6): 619–632. doi:10.1021/cr00058a002

Hemiacetal

Disulfiram-alcohol reaction

Medical condition

"Isolation and structure of coprine, a novel physiologically active cyclopropanone derivative from Coprinus atramentarius and its synthesis via 1-aminocyclopropanol"

Disulfiram-alcohol reaction

Disulfiram-alcohol_reaction

Ketone

Organic compounds of the form >C=O

simplest class have the formula (CH2)nCO, where n varies from 2 for cyclopropanone ((CH2)2CO) to the tens. Larger derivatives exist. Cyclohexanone ((CH2)5CO)

Ketone

C3H4O

Index of chemical compounds with the same molecular formula

; Berdahl, Donald R.; Lu, Ta-Jung (1987-10-28), "The Chemistry of Cyclopropanones", in Rappoport, Zvi (ed.), Cyclopropyl Group Volume 1 and Volume 2

C3H4O

Lithium naphthalenide

Chemical compound

David G. Hilmey; Leo A. Paquette (2007). "1,3-Dichloroacetone as a Cyclopropanone Equivalent: 5-Oxaspiro[3.4]Octan-1-one". Organic Syntheses. 84: 156

Lithium naphthalenide

Lithium_naphthalenide

Cyclopropanetrione

Chemical compound

groups. Corkran, Greg; David W. Ball (2004). "The relative energies of cyclopropanone, cyclopropanedione, and cyclopropanetrione. Hartree–Fock, density-functional

Cyclopropanetrione

Ion-exchange resin

Organic polymer matrix bearing ion-exchange functional groups

David G. Hilmey; Leo A. Paquette (2007). "1,3-Dichloroacetone as a Cyclopropanone Equivalent: 5-oxaspiro[3.4]octan-1-one". Org. Synth. 84: 156. doi:10

Ion-exchange resin

Ion-exchange_resin

List of compounds with carbon number 3

difluoroacetate 433-53-4 C3H4N2 methyleneaminoacetonitrile 109-82-0 C3H4O cyclopropanone 5009-27-8 C3H4O methoxyacetylene 6443-91-0 C3H4O methylketene 6004-44-0

List of compounds with carbon number 3

List_of_compounds_with_carbon_number_3

(4+3) cycloaddition

Chemical reaction

required to stabilize the oxyallyl cation and prevent isomerization to cyclopropanones and allene oxides. In most cases, an excess of the diene is employed

(4+3) cycloaddition

(4+3)_cycloaddition

Homo-Favorskii rearrangement

Rearrangement of β-halo ketones and cyclobutanones

that of the Favorskii rearrangement. The major difference is that the cyclopropanone intermediate is replaced by a cyclobutanone intermediate, and therefore

Homo-Favorskii rearrangement

Homo-Favorskii_rearrangement

Alcohol oxidase

Class of enzymes

include H2O2, Cu2+, phenanthroline, acetamide, potassium cyanide, or cyclopropanone. SCAO is an intracellular enzyme. Its common source are fungi and yeasts

Alcohol oxidase

Alcohol_oxidase

Tetrahedral carbonyl addition compound

Chemical reaction intermediate

readily because its substituents are very small- a purely steric effect. Cyclopropanones- three-membered ring ketones- are also hydrated to a significant extent

Tetrahedral carbonyl addition compound

Tetrahedral_carbonyl_addition_compound

Jerome A. Berson

American chemist (1924–2017)

effects on the rates of stereomutation of a pair of diastereomeric cyclopropanones. Ground state stabilization in nucleophilic solvents induces deviation

Jerome A. Berson

Jerome_A._Berson

Reductive dehalogenation of halo ketones

of dienes or olefins. Isomerization of 2-oxyallyl metal complexes to cyclopropanone and allene oxide forms is rapid and reversible; increasing the covalent

Reductive dehalogenation of halo ketones

Reductive_dehalogenation_of_halo_ketones

Allene oxide

require steric protection for their isolation. They readily rearrange to cyclopropanones via an oxyallyl intermediate. Despite the esoteric character of synthetic

Allene oxide

Allene_oxide

Non-Kekulé molecule

This reactive intermediate is postulated to occur in ring opening of cyclopropanones, allene oxides and in the Favorskii rearrangement. The intermediate

Non-Kekulé molecule

Non-Kekulé_molecule

Dichlorocarbene

Chemical compound

dichlorocyclopropanes. These can be reduced to cyclopropanes or hydrolysed to give cyclopropanones by a geminal halide hydrolysis. Dichlorocyclopropanes may also be converted

Dichlorocarbene