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A nitronate (IUPAC: azinate) in organic chemistry is an anion with the general structure R1R2C=N+(−O−)2, containing the =N+(−O−)2 functional group, where
Nitronate
Chemical reaction; acid hydrolysis of a nitroalkane salt to a ketone
sulfuric acid to acetophenone. The reaction mechanism starting from the nitronate salt as the resonance structures 1a and 1b is depicted below: The salt
Nef_reaction
Class of enzymes
Nitronate monooxygenase (EC 1.13.12.16, NMO) is an enzyme with systematic name nitronate:oxygen 2-oxidoreductase (nitrite-forming). This enzyme catalyses
Nitronate_monooxygenase
Organic compound containing an –NO2 group
Nitrosating a nitronate gives a nitrolic acid. Nitronates are also key intermediates in the Nef reaction: when exposed to acids or oxidants, a nitronate hydrolyzes
Nitro_compound
Chemical reaction
begins with the deprotonation of 2-nitropropane at the α carbon to form a nitronate. This compound then initiates an SN2 reaction to displace the benzyl halide
Hass–Bender_oxidation
Chemical reaction
nitroalkanes to give nitronate alkoxides that yield mainly syn-nitro alcohols once protonated, and finally generation of nitronate anions in which one
Henry_reaction
Class of enzymes
also called propionate-3-nitronate oxidase. It employs one cofactor, FMN. Porter DJ, Bright HJ (1987). "Propionate-3-nitronate oxidase from Penicillium
3-aci-nitropropanoate_oxidase
Chemical reaction
reaction) is the nucleophilic addition of a nitroalkane (or the corresponding nitronate anion) to an imine, resulting in the formation of a beta-nitroamine. With
Nitro-Mannich_reaction
using nitroethane. The reaction proceeds via the intermediacy of the nitronate anion. Most nitrolic acids are laboratory curiosities. One exception is
Nitrolic_acid
Chemical compound
Conversion of Nitro to Carbonyl Group by Dimethyldioxirane (DMD) Oxidation of Nitronate Anions". Synlett. 1998 (12): 1335–1336. doi:10.1055/s-1998-1947.
Dimethyldioxirane
Reaction in organic chemistry
Melton, J. (1988). "Conversion of Nitro to Carbonyl by Ozonolysis of Nitronates: 2,5-Heptanedione". Organic Syntheses; Collected Volumes, vol. 6, p. 648
Michael_addition_reaction
Topics referred to by the same term
power from a signal in an adjacent channel An alternate name for the nitronate moiety Application container image, a specification for the format and
ACI
Organic compounds of the form –C(=O)N(OH)–
primary nitro compounds kept in an acidic solution (to minimize the nitronate tautomer) hydrolyze to a hydroxamic acid. In base, the reaction requires
Hydroxamic_acid
Chemical theory about acids and bases
poorly. Violations occur with cyanide, cyanate, thiocyanate, nitrite, nitronates, amide enaminols, and phenylsulfinate. Instead, the determining factor
HSAB_theory
Chemical group (>C=N(O)–)
g. metals, SO2) deoxygenate to the imine instead. N-Oxoammonium salt Nitronate Hamer, Jan; Macaluso, Anthony (1964-08-01). "Nitrones". Chemical Reviews
Nitrone
Topics referred to by the same term
disease or Devic's syndrome N-Methylmorpholine N-oxide, an organic compound Nitronate monooxygenase, an enzyme Normal Move Out, in reflection seismology National
NMO
Chemical compound
Jack Melton (1977). "Conversion of Nitro to Carbonyl by Ozonolysis of Nitronates: 2,5-Heptanedione". Organic Syntheses. 56: 36. doi:10.15227/orgsyn.056
Diisopropylamine
Chemical compound with four carbon rings sharing a single carbon atom
step with 1-nitrocyclopentene 3 in a nucleophilic addition whereby the nitronate 4 is captured by phenylselenenyl bromide to the selenium intermediate
Fenestrane
11.31: arachidonate 12-lipoxygenase EC 1.13.11.32: Now EC 1.13.12.16, nitronate monooxygenase EC 1.13.11.33: arachidonate 15-lipoxygenase EC 1.13.11.34:
List_of_EC_numbers_(EC_1)
Compounds with similar properties to polyatomic halogens
Oxides". In Feuer, Henry [in German] (ed.). Nitrile Oxides, Nitrones, and Nitronates in Organic Synthesis: Novel Strategies in Synthesis (2nd ed.). Hoboken
Pseudohalogen
Organic ion with a negatively charged carbon atom
with neighboring conjugating groups (e.g., allylic anions, enolates, nitronates, etc.) are generally planar rather than pyramidized. Likewise, delocalized
Carbanion
Typer of isomerization
(figure 1). It is proposed that activation occurs via H–bonding of both the nitronate and the ester to the thiourea catalyst and explains the interesting selectivity
Cycloisomerization
Latvian chemist
molecular structure of 2-nitro-1,3-indandione dihydrate. A hydronium nitronate". Acta Crystallographica B. B33 (10): 3045–3049. doi:10.1107/S0567740877010231
Gustavs_Vanags
Chemical compound
Sukhorukov (2023). "Reductive Denitrogenation of Six-membered Cyclic Nitronates to Densely Substituted Dihydrofurans with Raney® Nickel/AcOH System".
2,3-Dihydrofuran
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Boy/Male
Tamil
Lord Shiva, A name of Lord Rama
Female
Hungarian
Pet form of Hungarian Györgyi, GYÖRGYIKE means "earth-worker, farmer."
Girl/Female
Muslim
Diamond
Girl/Female
American, British, Christian, English, French, Indian, Parsi
Clear Blue Sky; Sky Blue
Girl/Female
Hindu
Heroic girl
Surname or Lastname
English
English : from the personal name Perceval, first found as the name of the hero of an epic poem by the 12th-century French poet Crestien de Troyes, describing the quest for the holy grail. The origin of the name is uncertain; it may be associated with the Gaulish personal name Pritorīx or it may be an alteration of the Celtic name Peredur (see Priddy). It seems to have been altered as the result of folk etymological association with Old French perce(r) ‘to pierce or breach’ + val ‘valley’.English : Norman habitational name from either of the two places in Calvados named Perceval.
Girl/Female
Australian, Hebrew
Princess; Form of Sarah
Boy/Male
Indian
Congratulations, Blessed
Girl/Female
Muslim/Islamic
Clean
Girl/Female
Muslim
Scholar, A narrator of Hadith
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